Polyoxometalates (POMs): from electroactive clusters to energy materials
نویسندگان
چکیده
Polyoxometalates as anionic molecular metal oxides clusters with open frameworks and rich redox chemistry have outstanding versatility in energy conversion storage research.
منابع مشابه
Polyoxometalates: from inorganic chemistry to materials science.
Polyoxometalates have been traditionally the subject of study of molecular inorganic chemistry. Yet, these polynuclear molecules, reminiscent of oxide clusters, present a wide range of structures and with them ideal frameworks for the deployment of a plethora of useful magnetic, electroionic, catalytic, bioactive and photochemical properties. With this in mind, a new trend towards the applicati...
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15 صفحه اولDMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates.
We have demonstrated that a pentaerythritol-derivatized hexavanadate can be easily esterified with acid anhydrides using 4-(N,N-dimethylamino)pyridine (DMAP) as a catalyst, which provides a convenient method for the functionalization of polyoxometalates.
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This review describes the synthesis and characterization of inorganic materials containing polyoxometalates encapsulated in oxide matrices. Examples illustrating key aspects in terms of synthesis and applications are presented according to the nature of the final hybrid material: those based on non-structured silicas, on mesostructured silicas, on macrostructured silicas and on other oxides. In...
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In this paper, the main objective is to provide an overview of a new class of research problems for the area which is broadly termed smart structures control. To this end, we describe electroactive smart materials and focus on control issues which naturally arise. Such materials, typically nano and micro-polymers, have mechanical properties controlled by an electric field. Unlike existing appro...
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ژورنال
عنوان ژورنال: Energy and Environmental Science
سال: 2021
ISSN: ['1754-5706', '1754-5692']
DOI: https://doi.org/10.1039/d0ee03407j